Chemoselective carbene insertion into the N−H bonds of NH(3)·H(2)O

The conversion of inexpensive aqueous ammonia (NH(3)·H(2)O) into value-added primary amines by N−H insertion persists as a longstanding challenge in chemistry because of the tendency of Lewis basic ammonia (NH(3)) to bind and inhibit metal catalysts. Herein, we report a chemoselective carbene N−H in...

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Detalles Bibliográficos
Autores principales: Liu, Zhaohong, Yang, Yong, Song, Qingmin, Li, Linxuan, Zanoni, Giuseppe, Liu, Shaopeng, Xiang, Meng, Anderson, Edward A., Bi, Xihe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9741638/
https://www.ncbi.nlm.nih.gov/pubmed/36496464
http://dx.doi.org/10.1038/s41467-022-35394-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9741638/
https://www.ncbi.nlm.nih.gov/pubmed/36496464
http://dx.doi.org/10.1038/s41467-022-35394-z

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