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Chemoselective carbene insertion into the N−H bonds of NH(3)·H(2)O
The conversion of inexpensive aqueous ammonia (NH(3)·H(2)O) into value-added primary amines by N−H insertion persists as a longstanding challenge in chemistry because of the tendency of Lewis basic ammonia (NH(3)) to bind and inhibit metal catalysts. Herein, we report a chemoselective carbene N−H in...
Autores principales: | Liu, Zhaohong, Yang, Yong, Song, Qingmin, Li, Linxuan, Zanoni, Giuseppe, Liu, Shaopeng, Xiang, Meng, Anderson, Edward A., Bi, Xihe |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9741638/ https://www.ncbi.nlm.nih.gov/pubmed/36496464 http://dx.doi.org/10.1038/s41467-022-35394-z |
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