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Directed Diastereoselective Cyclopropanation and Epoxidation of Alkenyl Cyclopropyl Carbinol Derivatives

[Image: see text] We report the directed diastereoselective Simmons–Smith cyclopropanation and vanadium-catalyzed epoxidation reactions of alkenyl cyclopropyl carbinol derivatives. The reaction furnished densely substituted stereodefined bicyclopropanes and cyclopropyl oxiranes as a single diastereo...

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Detalles Bibliográficos
Autores principales: Cohen, Anthony, Siddaraju, Yogesh, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9743385/
https://www.ncbi.nlm.nih.gov/pubmed/36354275
http://dx.doi.org/10.1021/acs.orglett.2c03305