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Phosphinophosphoranes: Mixed-Valent Phosphorus Compounds with Ambiphilic Properties
[Image: see text] Herein, we present a simple synthesis of mixed-valent phosphinophosphoranes bearing three- and five-coordinate phosphorus centers. Compounds with phosphorus–phosphorus bonds were synthesized via a reaction of lithium phosphides RR′PLi with cat(2)PCl (cat = catecholate), whereas der...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749023/ https://www.ncbi.nlm.nih.gov/pubmed/36453123 http://dx.doi.org/10.1021/acs.inorgchem.2c03166 |