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Phosphinophosphoranes: Mixed-Valent Phosphorus Compounds with Ambiphilic Properties

[Image: see text] Herein, we present a simple synthesis of mixed-valent phosphinophosphoranes bearing three- and five-coordinate phosphorus centers. Compounds with phosphorus–phosphorus bonds were synthesized via a reaction of lithium phosphides RR′PLi with cat(2)PCl (cat = catecholate), whereas der...

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Detalles Bibliográficos
Autores principales: Szynkiewicz, Natalia, Chojnacki, Jarosław, Grubba, Rafał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749023/
https://www.ncbi.nlm.nih.gov/pubmed/36453123
http://dx.doi.org/10.1021/acs.inorgchem.2c03166