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Not All (3)MC States Are the Same: The Role of (3)MC(cis) States in the Photochemical N(∧)N Ligand Release from [Ru(bpy)(2)(N(∧)N)](2+) Complexes

[Image: see text] Ruthenium(II) complexes feature prominently in the development of agents for photoactivated chemotherapy; however, the excited-state mechanisms by which photochemical ligand release operates remain unclear. We report here a systematic experimental and computational study of a serie...

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Detalles Bibliográficos
Autores principales: Eastham, Katie, Scattergood, Paul A., Chu, Danny, Boota, Rayhaan Z., Soupart, Adrien, Alary, Fabienne, Dixon, Isabelle M., Rice, Craig R., Hardman, Samantha J. O., Elliott, Paul I. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749030/
https://www.ncbi.nlm.nih.gov/pubmed/36450138
http://dx.doi.org/10.1021/acs.inorgchem.2c03146