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Bidentate substrate binding in Brønsted acid catalysis: structural space, hydrogen bonding and dimerization

BINOL derived chiral phosphoric acids (CPAs) are a prominent class of catalysts in the field of asymmetric organocatalysis, capable of transforming a wide selection of substrates with high stereoselectivities. Exploiting the Brønsted acidic and basic dual functionality of CPAs, substrates with both...

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Detalles Bibliográficos
Autores principales: Gramüller, Johannes, Dullinger, Philipp, Horinek, Dominik, Gschwind, Ruth M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749107/
https://www.ncbi.nlm.nih.gov/pubmed/36545144
http://dx.doi.org/10.1039/d2sc05076e