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Three-component carboformylation: α-quaternary aldehyde synthesis via Co(iii)-catalysed sequential C–H bond addition to dienes and acetic formic anhydride

All carbon α-quaternary aldehydes are prepared via Co(iii)-catalysed sequential C–H bond addition to dienes and acetic formic anhydride, representing a rare example of intermolecular carboformylation. A wide range of internally substituted dienes containing diverse functionality can be employed in t...

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Detalles Bibliográficos
Autores principales: Tassone, Joseph P., Yeo, Jihyeon, Ellman, Jonathan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749387/
https://www.ncbi.nlm.nih.gov/pubmed/36545136
http://dx.doi.org/10.1039/d2sc05599f