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Trapping the Transition State in a [2,3]-Sigmatropic Rearrangement by Applying Pressure

[Image: see text] Transition states are of central importance in chemistry. While they are, by definition, transient species, it has been shown before that it is possible to “trap” transition states by applying stretching forces. We here demonstrate that the task of transforming the transition state...

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Detalles Bibliográficos
Autores principales: Kumar, Sourabh, Weiß, Rahel, Zeller, Felix, Neudecker, Tim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9753542/
https://www.ncbi.nlm.nih.gov/pubmed/36530272
http://dx.doi.org/10.1021/acsomega.2c05664