Cargando…
Origin of the Ligand Ring‐Size Effect on the Catalytic Activity of Cationic Calcium Hydride Dimers in the Hydrogenation of Unactivated 1‐Alkenes
Recently, it was shown that the double Ca−H−Ca‐bridged calcium hydride cation dimer [LCaH(2)CaL](2+) when stabilized by a larger macrocyclic N,N’,N’’,N’’’,N’’’’‐pentadentate ligand showed evidently higher activity than when stabilized by a smaller N,N’,N’’,N’’’‐tetradentate ligand in the catalytic h...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9756592/ https://www.ncbi.nlm.nih.gov/pubmed/36524742 http://dx.doi.org/10.1002/open.202200240 |