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Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Applying sequential Diels–Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in...

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Detalles Bibliográficos
Autores principales: Rajagopal, Shinaj K., Dishi, Or, Bogoslavsky, Benny, Gidron, Ori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9756652/
https://www.ncbi.nlm.nih.gov/pubmed/36412186
http://dx.doi.org/10.1039/d2cc05434e