Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Applying sequential Diels–Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in...

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Autores principales: Rajagopal, Shinaj K., Dishi, Or, Bogoslavsky, Benny, Gidron, Ori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9756652/
https://www.ncbi.nlm.nih.gov/pubmed/36412186
http://dx.doi.org/10.1039/d2cc05434e
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author Rajagopal, Shinaj K.
Dishi, Or
Bogoslavsky, Benny
Gidron, Ori
author_facet Rajagopal, Shinaj K.
Dishi, Or
Bogoslavsky, Benny
Gidron, Ori
author_sort Rajagopal, Shinaj K.
collection PubMed
description Applying sequential Diels–Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.
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spelling pubmed-97566522022-12-20 Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes Rajagopal, Shinaj K. Dishi, Or Bogoslavsky, Benny Gidron, Ori Chem Commun (Camb) Chemistry Applying sequential Diels–Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials. The Royal Society of Chemistry 2022-11-16 /pmc/articles/PMC9756652/ /pubmed/36412186 http://dx.doi.org/10.1039/d2cc05434e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Rajagopal, Shinaj K.
Dishi, Or
Bogoslavsky, Benny
Gidron, Ori
Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title_full Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title_fullStr Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title_full_unstemmed Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title_short Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
title_sort transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9756652/
https://www.ncbi.nlm.nih.gov/pubmed/36412186
http://dx.doi.org/10.1039/d2cc05434e
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