Cargando…
Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes
Applying sequential Diels–Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in...
Autores principales: | Rajagopal, Shinaj K., Dishi, Or, Bogoslavsky, Benny, Gidron, Ori |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9756652/ https://www.ncbi.nlm.nih.gov/pubmed/36412186 http://dx.doi.org/10.1039/d2cc05434e |
Ejemplares similares
-
Alternating behavior in furan-acetylene macrocycles reveals the size-dependency of Hückel’s rule in neutral molecules
por: Rahav, Yuval, et al.
Publicado: (2023) -
A macrocyclic oligofuran: synthesis, solid state structure and electronic properties
por: Mulay, Sandip V., et al.
Publicado: (2019) -
A Macrocyclic Furan with Accessible Oxidation States: Switching Between Aromatic and Antiaromatic Global Ring Currents
por: Dishi, Or, et al.
Publicado: (2022) -
Controlling the helicity of π-conjugated oligomers by tuning the aromatic backbone twist
por: Bedi, Anjan, et al.
Publicado: (2022) -
Functional group introduction and aromatic unit variation in a set of π-conjugated macrocycles: revealing the central role of local and global aromaticity
por: Rimmele, Martina, et al.
Publicado: (2021)