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Exploring fluoride effects in sterically enhanced cobalt ethylene polymerisation catalysts; a combined experimental and DFT study
The fluoro-substituted 2,6-bis(arylimino)pyridine dichlorocobalt complexes, [2-{CMeN(2,6-(Ph(2)CH)(2)-3,4-F(2)C(6)H)}-6-(CMeNAr)C(5)H(3)N]CoCl(2) (Ar = 2,6-Me(2)C(6)H(3) Co1, 2,6-Et(2)C(6)H(3)Co2, 2,6-iPr(2)C(6)H(3)Co3, 2,4,6-Me(3)C(6)H(2)Co4, 2,6-Et-4-MeC(6)H(2)Co5), were synthesized in good yield...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9761560/ https://www.ncbi.nlm.nih.gov/pubmed/36545290 http://dx.doi.org/10.1039/d2ra05806e |