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Exploring fluoride effects in sterically enhanced cobalt ethylene polymerisation catalysts; a combined experimental and DFT study

The fluoro-substituted 2,6-bis(arylimino)pyridine dichlorocobalt complexes, [2-{CMeN(2,6-(Ph(2)CH)(2)-3,4-F(2)C(6)H)}-6-(CMeNAr)C(5)H(3)N]CoCl(2) (Ar = 2,6-Me(2)C(6)H(3) Co1, 2,6-Et(2)C(6)H(3)Co2, 2,6-iPr(2)C(6)H(3)Co3, 2,4,6-Me(3)C(6)H(2)Co4, 2,6-Et-4-MeC(6)H(2)Co5), were synthesized in good yield...

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Detalles Bibliográficos
Autores principales:	Li, Zilong, Ma, Yanping, Liu, Tian, Zhang, Qiuyue, Solan, Gregory A., Liang, Tongling, Sun, Wen-Hua
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9761560/ https://www.ncbi.nlm.nih.gov/pubmed/36545290 http://dx.doi.org/10.1039/d2ra05806e

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