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Visible-light-driven proton reduction for semi-hydrogenation of alkynes via organophotoredox/manganese dual catalysis

Described here is a unprecedented organophotoredox/manganese dual catalyzed proton reduction and its application for semi-reduction of alkynes. The catalytic active pre-catalyst [Mn-1] can be feasibly be prepared on gram-scale from Mn(acac)(2)·2H(2)O in air. This dual catalytic protocol features nob...

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Detalles Bibliográficos
Autores principales: Wang, Xiao-Yu, He, Yong-Qin, Wang, Mei, Zhou, Yi, Li, Na, Song, Xian-Rong, Zhou, Zhao-Zhao, Tian, Wan-Fa, Xiao, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9761695/
https://www.ncbi.nlm.nih.gov/pubmed/36545070
http://dx.doi.org/10.1039/d2ra07920h