Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr(11)M(2)} complexes

Addition of 1,4,8,11-tetrazacyclotetradecane (cyclam) to a reaction that produces octametallic rings when simpler amines are used, produces {Cr(11)M(2)} “pretzels” (M = Zn(II) or Cu(II)) where the cyclam coordinates to the M(II) ion which then sits at the centre of a twelve-metal macrocycle. Magneti...

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Detalles Bibliográficos
Autores principales: Alotaibi, Rajeh, Brookfield, Adam, Fowler, Jonathan M., Whitehead, George F. S., Lockyer, Selena J., Timco, Grigore A., Collison, David, Schnack, Jürgen, Winpenny, Richard E. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9764323/
https://www.ncbi.nlm.nih.gov/pubmed/36477464
http://dx.doi.org/10.1039/d2dt03368b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9764323/
https://www.ncbi.nlm.nih.gov/pubmed/36477464
http://dx.doi.org/10.1039/d2dt03368b

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