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Role of the Meso Substituent in Defining the Reduction of Uranyl Dipyrrin Complexes

[Image: see text] The uranyl complex U(VI)O(2)Cl(L(Mes)) of the redox-active, acyclic dipyrrin–diimine anion L(Mes–) [HL(Mes) = 1,9-di-tert-butyl-imine-5-(mesityl)dipyrrin] is reported, and its redox property is explored and compared with that of the previously reported U(VI)O(2)Cl(L(F)) [HL(F) = 1,...

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Detalles Bibliográficos
Autores principales: van Rees, Karlotta, Rajeshkumar, Thayalan, Maron, Laurent, Sproules, Stephen, Love, Jason B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9768749/
https://www.ncbi.nlm.nih.gov/pubmed/36472325
http://dx.doi.org/10.1021/acs.inorgchem.2c03048