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Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand

[Image: see text] Cyclobutadienyl complexes of the f-elements are a relatively new yet poorly understood class of sandwich and half-sandwich organometallic compounds. We now describe cyclobutadienyl transfer reactions of the magnesium reagent [(η(4)-Cb'''')Mg(THF)(3)] (1), where...

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Detalles Bibliográficos
Autores principales: Tsoureas, Nikolaos, Rajeshkumar, Thayalan, Townrow, Oliver P. E., Maron, Laurent, Layfield, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9768750/
https://www.ncbi.nlm.nih.gov/pubmed/36484644
http://dx.doi.org/10.1021/acs.inorgchem.2c03534