Cargando…

Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand

[Image: see text] Cyclobutadienyl complexes of the f-elements are a relatively new yet poorly understood class of sandwich and half-sandwich organometallic compounds. We now describe cyclobutadienyl transfer reactions of the magnesium reagent [(η(4)-Cb'''')Mg(THF)(3)] (1), where...

Descripción completa

Detalles Bibliográficos
Autores principales:	Tsoureas, Nikolaos, Rajeshkumar, Thayalan, Townrow, Oliver P. E., Maron, Laurent, Layfield, Richard A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9768750/ https://www.ncbi.nlm.nih.gov/pubmed/36484644 http://dx.doi.org/10.1021/acs.inorgchem.2c03534

Ejemplares similares

Synthesis, bonding properties and ether activation reactivity of cyclobutadienyl-ligated hybrid uranocenes
por: Tsoureas, Nikolaos, et al.
Publicado: (2021)

Heteroleptic actinocenes: a thorium(iv)–cyclobutadienyl–cyclooctatetraenyl–di-potassium-cyclooctatetraenyl complex
por: Boronski, Josef T., et al.
Publicado: (2020)

Uranium and thorium complexes of the phosphaethynolate ion
por: Camp, Clément, et al.
Publicado: (2015)

Dinitrogen cleavage by a dinuclear uranium(iii) complex
por: Jori, Nadir, et al.
Publicado: (2023)

Cation assisted binding and cleavage of dinitrogen by uranium complexes
por: Jori, Nadir, et al.
Publicado: (2022)

Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes
por: Xin, Xiaoqing, et al.
Publicado: (2022)

Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
por: Su, Wei, et al.
Publicado: (2022)

Dominance of Cyclobutadienyl Over Cyclopentadienyl in the Crystal Field Splitting in Dysprosium Single‐Molecule Magnets
por: Durrant, James P., et al.
Publicado: (2022)

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides
por: Du, Jingzhen, et al.
Publicado: (2019)

Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
por: Lu, Erli, et al.
Publicado: (2018)

Manual on radiological safety in uranium and thorium mines and mills
por: International Atomic Energy Agency. Vienna
Publicado: (1976)

Determination of Traces of Uranium and Thorium in Microelectronics Constituent Materials
por: Saisho, Hideo, et al.
Publicado: (1988)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Enhanced diffusion of Uranium and Thorium linked to crystal plasticity in zircon
por: Timms, Nicholas E, et al.
Publicado: (2006)

Interactions of proton and heavy ion beams with uranium and thorium targets
por: Barashenkov, V S, et al.
Publicado: (1996)

Fission of uranium, thorium and bismuth by 20 GeV protons
por: De Carvalho, H G, et al.
Publicado: (1962)

Monitoring and surveillance of residues from the mining and milling of uranium and thorium
por: International Atomic Energy Agency. Vienna
Publicado: (2002)

Alkyl-Substituted Aminobis(phosphonates)—Efficient Precipitating Agents for Rare Earth Elements, Thorium, and Uranium in Aqueous Solutions
por: Virtanen, Emilia J., et al.
Publicado: (2021)

Reduced Arene Complexes of Hafnium Supported by a Triamidoamine Ligand
por: Ghana, Priyabrata, et al.
Publicado: (2021)

Solvent‐Dependent Oxidative Addition and Reductive Elimination of H(2) Across a Gallium‐Zinc Bond
por: Morris, Louis J., et al.
Publicado: (2022)

Safe management of wastes from the mining and milling of Uranium and Thorium ores
por: International Atomic Energy Agency. Vienna
Publicado: (1987)

Distribution of uranium and thorium chains radionuclides in different fractions of phosphogypsum grains
por: Szajerski, Piotr
Publicado: (2020)

A comparison of the chemo- and radiotoxicity of thorium and uranium at different enrichment grades
por: Rump, A., et al.
Publicado: (2023)

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand
por: Modder, Dieuwertje K., et al.
Publicado: (2022)

The formation mechanism of uranium and thorium hydride phosphorus: a systematically theoretical study
por: Zhao, Huifeng, et al.
Publicado: (2019)

Determination of Trace Thorium and Uranium Impurities in Scandium with High Matrix by ICP-OES
por: She, Zhixuan, et al.
Publicado: (2023)

Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron
por: Witteman, Léon, et al.
Publicado: (2018)

A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN‐Macrocycle Supported [Ga(I)](+) and [Ga(III)H](2+)
por: Morris, Louis J., et al.
Publicado: (2022)

Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)‐Centre: Labile Mono‐ and Bis(hydridogallyl)zinc Complexes
por: Morris, Louis J., et al.
Publicado: (2022)

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
por: Du, Jingzhen, et al.
Publicado: (2021)

Release and yields from thorium and uranium targets irradiated with a pulsed proton beam
por: Evensen, A H M, et al.
Publicado: (1997)

Evaluation of polybenzimidazole-based polymers for the removal of uranium, thorium and palladium from aqueous medium
por: Kumar, V. Vijaya, et al.
Publicado: (2018)

Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides
por: Shephard, Jacob J., et al.
Publicado: (2022)

Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states
por: Wedal, Justin C., et al.
Publicado: (2021)

Mineralogical Properties of a Refractory Tantalum-Niobium Slag and the Effect of Roasting on the Leaching of Uranium-Thorium
por: Huang, Min, et al.
Publicado: (2022)

Steric control of redox events in organo-uranium chemistry: synthesis and characterisation of U(v) oxo and nitrido complexes
por: Tsoureas, Nikolaos, et al.
Publicado: (2016)

Intramolecular Halo Stabilization of Silyl Cations—Silylated Halonium‐ and Bis‐Halo‐Substituted Siliconium Borates
por: Merk, Anastasia, et al.
Publicado: (2021)

Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes
por: Zitz, Rainer, et al.
Publicado: (2017)

Electron Shuttle in N-Heteroaromatic Ni Catalysts for Alkene Isomerization
por: Tricoire, Maxime, et al.
Publicado: (2022)

Correction to “Electron Shuttle in N-Heteroaromatic Ni Catalysts for Alkene Isomerization”
por: Tricoire, Maxime, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_12ss5ks15c642okq9gfu4t6f9k