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Gold(I)···Lanthanide(III) Bonds in Discrete Heterobimetallic Compounds: A Combined Computational and Topological Study

[Image: see text] The chemical nature of the ligand-unsupported gold(I)–lanthanide(III) bond in the proposed [Ln(III)(η(5)-Cp)(2)][Au(I)Ph(2)] (Ln–Au; Ln(III) = La(III), Eu(III), or Lu(III); Cp = cyclopentadienide; Ph = phenyl) models is examined from a theoretical viewpoint. The covalent bond-like...

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Detalles Bibliográficos
Autores principales: Blasco, Daniel, Sundholm, Dage
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9768751/
https://www.ncbi.nlm.nih.gov/pubmed/36475614
http://dx.doi.org/10.1021/acs.inorgchem.2c02717