Catalysis enabled synthesis, structures, and reactivities of fluorinated S(8)-corona[n]arenes (n = 8–12)

Previously inaccessible large S(8)-corona[n]arene macrocycles (n = 8–12) with alternating aryl and 1,4-C(6)F(4) subunits are easily prepared on up to gram scales, without the need for chromatography (up to 45% yield, 10 different examples) through new high acceleration S(N)Ar substitution protocols...

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Detalles Bibliográficos
Autores principales: Turley, Andrew. T., Hanson-Heine, Magnus W. D., Argent, Stephen. P., Hu, Yaoyang, Jones, Thomas. A., Fay, Michael, Woodward, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769089/
https://www.ncbi.nlm.nih.gov/pubmed/36605745
http://dx.doi.org/10.1039/d2sc05348a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769089/
https://www.ncbi.nlm.nih.gov/pubmed/36605745
http://dx.doi.org/10.1039/d2sc05348a

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