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Catalysis enabled synthesis, structures, and reactivities of fluorinated S(8)-corona[n]arenes (n = 8–12)
Previously inaccessible large S(8)-corona[n]arene macrocycles (n = 8–12) with alternating aryl and 1,4-C(6)F(4) subunits are easily prepared on up to gram scales, without the need for chromatography (up to 45% yield, 10 different examples) through new high acceleration S(N)Ar substitution protocols...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769089/ https://www.ncbi.nlm.nih.gov/pubmed/36605745 http://dx.doi.org/10.1039/d2sc05348a |