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Equilibrating parent aminomercaptocarbene and CO(2) with 2-amino-2-thioxoacetic acid via heavy-atom quantum tunneling
The search for methods to bind CO(2) and use it synthetically as a C(1)-building block under mild conditions is an ongoing endeavor of great urgency. The formation of heterocyclic carbene–carbon dioxide adducts occurs rapidly when the carbene is generated in solution in the presence of CO(2). Here w...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769125/ https://www.ncbi.nlm.nih.gov/pubmed/36605744 http://dx.doi.org/10.1039/d2sc05388h |