Up-Scale Synthesis of p-(CH(2)=CH)C(6)H(4)CH(2)CH(2)CH(2)Cl and p-ClC(6)H(4)SiR(3) by CuCN-Catalyzed Coupling Reactions of Grignard Reagents with Organic Halides

[Image: see text] Grignard reagents featuring carbanion characteristics are mostly unreactive toward alkyl halides and require a catalyst for the coupling reaction. With the need to prepare p-(CH(2)=CH)C(6)H(4)CH(2)CH(2)CH(2)Cl on a large scale, the coupling reaction of p-(CH(2)=CH)C(6)H(4)MgCl with...

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Detalles Bibliográficos
Autores principales: Park, Ju Yong, Ko, Ji Hyeong, Lee, Hyun Ju, Park, Jun Hyeong, Lee, Junseong, Sa, Seokpil, Shin, Eun Ji, Lee, Bun Yeoul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9773938/
https://www.ncbi.nlm.nih.gov/pubmed/36570214
http://dx.doi.org/10.1021/acsomega.2c05951

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9773938/
https://www.ncbi.nlm.nih.gov/pubmed/36570214
http://dx.doi.org/10.1021/acsomega.2c05951

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