Simultaneous Tunneling Control in Conformer-Specific Reactions

[Image: see text] We present here a new example of chemical reactivity governed by quantum tunneling, which also highlights the limitations of the classical theories. The syn and anti conformers of a triplet 2-formylphenylnitrene, generated in a nitrogen matrix, were found to spontaneously rearrange...

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Detalles Bibliográficos
Autores principales: Nunes, Cláudio M., Roque, José P. L., Doddipatla, Srinivas, Wood, Samuel A., McMahon, Robert J., Fausto, Rui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9776521/
https://www.ncbi.nlm.nih.gov/pubmed/36321916
http://dx.doi.org/10.1021/jacs.2c09026

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9776521/
https://www.ncbi.nlm.nih.gov/pubmed/36321916
http://dx.doi.org/10.1021/jacs.2c09026

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