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Simultaneous Tunneling Control in Conformer-Specific Reactions
[Image: see text] We present here a new example of chemical reactivity governed by quantum tunneling, which also highlights the limitations of the classical theories. The syn and anti conformers of a triplet 2-formylphenylnitrene, generated in a nitrogen matrix, were found to spontaneously rearrange...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9776521/ https://www.ncbi.nlm.nih.gov/pubmed/36321916 http://dx.doi.org/10.1021/jacs.2c09026 |