Cargando…
Functionalized Cyclopentenes via the Formal [4+1] Cycloaddition of Photogenerated Siloxycarbenes from Acyl Silanes
[Image: see text] This work describes the first formal cycloaddition reaction of photogenerated nucleophilic carbenes derived from acylsilanes with electrophilic dienes. The resulting transient donor–acceptor cyclopropane rearranges to its stable and highly functionalized cyclopentene isomer in an u...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9776530/ https://www.ncbi.nlm.nih.gov/pubmed/35736215 http://dx.doi.org/10.1021/acs.joc.2c00591 |