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Functionalized Cyclopentenes via the Formal [4+1] Cycloaddition of Photogenerated Siloxycarbenes from Acyl Silanes

[Image: see text] This work describes the first formal cycloaddition reaction of photogenerated nucleophilic carbenes derived from acylsilanes with electrophilic dienes. The resulting transient donor–acceptor cyclopropane rearranges to its stable and highly functionalized cyclopentene isomer in an u...

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Detalles Bibliográficos
Autores principales:	Vale, João R., Gomes, Rafael F., Afonso, Carlos A. M., Candeias, Nuno R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9776530/ https://www.ncbi.nlm.nih.gov/pubmed/35736215 http://dx.doi.org/10.1021/acs.joc.2c00591

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