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Samarium Diiodide Acting on Acetone—Modeling Single Electron Transfer Energetics in Solution

Samarium diiodide is a versatile single electron transfer (SET) agent with various applications in organic chemistry. Lewis structures regularly insinuate the existence of a ketyl radical when samarium diiodide binds a carbonyl group. The study presented here investigates this electron transfer by t...

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Detalles Bibliográficos
Autores principales: Steiner, Luca, Achazi, Andreas J., Vlaisavljevich, Bess, Miro, Pere, Paulus, Beate, Kelterer, Anne-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781745/
https://www.ncbi.nlm.nih.gov/pubmed/36557814
http://dx.doi.org/10.3390/molecules27248673