Cargando…

Samarium Diiodide Acting on Acetone—Modeling Single Electron Transfer Energetics in Solution

Samarium diiodide is a versatile single electron transfer (SET) agent with various applications in organic chemistry. Lewis structures regularly insinuate the existence of a ketyl radical when samarium diiodide binds a carbonyl group. The study presented here investigates this electron transfer by t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Steiner, Luca, Achazi, Andreas J., Vlaisavljevich, Bess, Miro, Pere, Paulus, Beate, Kelterer, Anne-Marie
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781745/ https://www.ncbi.nlm.nih.gov/pubmed/36557814 http://dx.doi.org/10.3390/molecules27248673

Ejemplares similares

Enabling Molecular-Level Computational Description of Redox and Proton-Coupled Electron Transfer Reactions of Samarium Diiodide
por: Himmelstrup, Jonas, et al.
Publicado: (2023)

Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations
por: Saadi, Jakub, et al.
Publicado: (2010)

Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
por: Sono, Masakazu, et al.
Publicado: (2012)

Preparation and Use of Samarium Diiodide (SmI(2)) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
por: Sadasivam, Dhandapani V., et al.
Publicado: (2013)

Bis(diethylenetriamine)cadmium(II) diiodide
por: Huang, Bei, et al.
Publicado: (2008)

3,6-Diazaoctane-1,8-diaminium diiodide
por: Cukrowski, Ignacy, et al.
Publicado: (2012)

Direct Growth of van der Waals Tin Diiodide Monolayers
por: Yuan, Qian‐Qian, et al.
Publicado: (2021)

Cucurbit[6]uril p-xylylenediammonium diiodide decahydrate inclusion complex
por: Huang, Wei-Hao, et al.
Publicado: (2008)

Hexaaquadodeca-μ(2)-chlorido-octahedro-hexaniobium diiodide
por: Schröder, Florian, et al.
Publicado: (2021)

First principle investigation of the linker length effects on the thermodynamics of divalent pseudorotaxanes
por: Achazi, Andreas J, et al.
Publicado: (2015)

Energy loss function of samarium
por: Yang, T. F., et al.
Publicado: (2023)

Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
por: Glatz, Mathias, et al.
Publicado: (2016)

Phosphinoindenyl and phosphazidoindenyl complexes of lanthanum and samarium: synthesis, characterisation, and hydroamination catalysis
por: Steiner, Matthias R., et al.
Publicado: (2021)

Samarium(II) folding cascades involving hydrogen atom transfer for the synthesis of complex polycycles
por: Plesniak, Mateusz P., et al.
Publicado: (2018)

{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)samarium(III) acetone solvate
por: Wang, Jing-Hua, et al.
Publicado: (2008)

Actinide arene-metalates: ion pairing effects on the electronic structure of unsupported uranium–arenide sandwich complexes
por: Murillo, Jesse, et al.
Publicado: (2021)

Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
por: Brewer, Greg, et al.
Publicado: (2009)

Hexaaquadodeca-μ(2)-iodido-octahedro-hexatantalum diiodide tetrahydrate
por: Schröder, Florian, et al.
Publicado: (2021)

Samarium Monosulfide (SmS): Reviewing Properties and Applications
por: Sousanis, Andreas, et al.
Publicado: (2017)

Samarium hexaboride is a trivial surface conductor
por: Hlawenka, P., et al.
Publicado: (2018)

Samarium Iodide Showcase: Unraveling the Mechanistic Puzzle
por: Hoz, Shmaryahu
Publicado: (2020)

Separation of samarium and europium by solvent extraction with an undiluted quaternary ammonium ionic liquid: towards high-purity medical samarium-153
por: Van de Voorde, Michiel, et al.
Publicado: (2018)

3,3′-Diethyl-1,1′-[anthracene-9,10-diylbis(oxyethylene)]diimidazolium diiodide
por: Hou, Yanhui
Publicado: (2009)

Photo-Induced Antitumor Effect of 3,6-Bis(1-methyl-4-vinylpyridinium) Carbazole Diiodide
por: Chou, Ya-Shuan, et al.
Publicado: (2013)

Giant isotropic negative thermal expansion in Y-doped samarium monosulfides by intra-atomic charge transfer
por: Takenaka, Koshi, et al.
Publicado: (2019)

Beyond Palliation: Therapeutic Applications of (153)Samarium-EDTMP
por: Wilky, Breelyn A., et al.
Publicado: (2013)

Screened moments and extrinsic in-gap states in samarium hexaboride
por: Fuhrman, W. T., et al.
Publicado: (2018)

Synthesis of Nitrogen Heterocycles Using Samarium(II) Iodide
por: Shi, Shicheng, et al.
Publicado: (2017)

Cerium and samarium blocked antioxidant enzymes in wheat plants
por: Haghighi, Amirhossein Kazemzadeh, et al.
Publicado: (2023)

Vibrational Excitation of Both Products of the Reaction of CN Radicals with Acetone in Solution
por: Dunning, Greg T., et al.
Publicado: (2015)

Light Increases Astaxanthin Absorbance in Acetone Solution through Isomerization Reactions
por: Virchenko, Oleksandr, et al.
Publicado: (2023)

Revealing extracellular electron transfer mediated parasitism: energetic considerations
por: Moscoviz, Roman, et al.
Publicado: (2017)

Energetics of the Electron Transfer Pathways in the Homodimeric Photosynthetic Reaction Center
por: Kanda, Tomoki, et al.
Publicado: (2022)

Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes
por: Xiao, Yuyuan, et al.
Publicado: (2020)

Di-μ-thiosemicarbazide-κ(4) S:S-bis[bis(thiosemicarbazide-κS)copper(I)] diiodide
por: Jia, Li, et al.
Publicado: (2008)

High-performance phononic crystal sensing structure for acetone solution concentration sensing
por: Fang, Tian-Yin, et al.
Publicado: (2023)

Lithium samarium polyphosphate, LiSm(PO(3))(4)
por: Zhao, Dan, et al.
Publicado: (2010)

Non-trivial surface states of samarium hexaboride at the (111) surface
por: Ohtsubo, Yoshiyuki, et al.
Publicado: (2019)

Structural and Chemical Properties of Geopolymer Gels Incorporated with Neodymium and Samarium
por: Nenadović, Snežana S. S., et al.
Publicado: (2021)

High-performance Acetone Soluble Tape Transfer Printing Method for Heterogeneous Integration
por: Zhang, Jiaqi, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_3qa0f0tmme3jossmloljoeufmr