Reinvestigating the Preferential Enrichment of DL-Arginine Fumarate: New Thoughts on the Mechanism of This Far from Equilibrium Crystallization Phenomenon

Preferential enrichment (PE) is a crystallization process, starting from either a racemic of slightly enantio-enriched solution (ca. +5%) that results in a high enantiomeric excess in the liquid phase (>+90%ee) and a slight opposite excess in the deposited crystals (−2 to −5%ee). The mechanism(s)...

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Detalles Bibliográficos
Autores principales: De Saint Jores, Clément, Brandel, Clément, Vaccaro, Marie, Gharbi, Najla, Schmitz-Afonso, Isabelle, Cardinael, Pascal, Tamura, Rui, Coquerel, Gérard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781920/
https://www.ncbi.nlm.nih.gov/pubmed/36557785
http://dx.doi.org/10.3390/molecules27248652

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781920/
https://www.ncbi.nlm.nih.gov/pubmed/36557785
http://dx.doi.org/10.3390/molecules27248652

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