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Reinvestigating the Preferential Enrichment of DL-Arginine Fumarate: New Thoughts on the Mechanism of This Far from Equilibrium Crystallization Phenomenon
Preferential enrichment (PE) is a crystallization process, starting from either a racemic of slightly enantio-enriched solution (ca. +5%) that results in a high enantiomeric excess in the liquid phase (>+90%ee) and a slight opposite excess in the deposited crystals (−2 to −5%ee). The mechanism(s)...
Autores principales: | De Saint Jores, Clément, Brandel, Clément, Vaccaro, Marie, Gharbi, Najla, Schmitz-Afonso, Isabelle, Cardinael, Pascal, Tamura, Rui, Coquerel, Gérard |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781920/ https://www.ncbi.nlm.nih.gov/pubmed/36557785 http://dx.doi.org/10.3390/molecules27248652 |
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