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Different Behavior of 2-Substituted 3-Nitro-2H-chromenes in the Reaction with Stabilized Azomethine Ylides Generated from α-Iminoesters

The AgOAc-catalysed reaction of 3-nitro-2-phenyl-2H-chromenes with stabilized azomethine ylides generated from the imines based on methyl glycinate and arylaldehydes leads to a mixture of endo and endo’ isomers of the corresponding chromeno[3,4-c]pyrrolidines in a ratio of 2.0–2.3:1 in 85–93% total...

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Detalles Bibliográficos
Autores principales: Kochnev, Ivan A., Barkov, Alexey Y., Simonov, Nikita S., Ulitko, Maria V., Zimnitskiy, Nikolay S., Korotaev, Vladislav Y., Sosnovskikh, Vyacheslav Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9784934/
https://www.ncbi.nlm.nih.gov/pubmed/36558115
http://dx.doi.org/10.3390/molecules27248983