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Carbonylation of Polyfluorinated 1-Arylalkan-1-ols and Diols in Superacids

We describe the carbonylation of a series of mono and dihydroxy derivatives of polyfluorinated alkylbenzenes and benzocycloalkenes with OH groups at benzylic positions using carbon monoxide in the presence of a superacid (TfOH, a TfOH–SbF(5) mixture, or a FSO(3)H–SbF(5) mixture). It was shown that t...

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Detalles Bibliográficos
Autores principales: Wang, Siqi, Zonov, Yaroslav V., Karpov, Victor M., Luzina, Olga A., Mezhenkova, Tatyana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9787639/
https://www.ncbi.nlm.nih.gov/pubmed/36557890
http://dx.doi.org/10.3390/molecules27248757