Synthesis and Functionalization of Tertiary Propargylic Boronic Esters by Alkynyllithium-Mediated 1,2-Metalate Rearrangement of Borylated Cyclopropanes

[Image: see text] Implementing the use of alkynyllithium reagents in a stereospecific 1,2-metalate rearrangement-mediated ring opening of polysubstituted cyclopropyl boronic esters provides a variety of tertiary pinacol boranes bearing adjacent tertiary or quaternary carbon stereocenters with high l...

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Detalles Bibliográficos
Autores principales: Pavlíčková, Tereza, Stöckl, Yannick, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9791689/
https://www.ncbi.nlm.nih.gov/pubmed/36446049
http://dx.doi.org/10.1021/acs.orglett.2c03756

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9791689/
https://www.ncbi.nlm.nih.gov/pubmed/36446049
http://dx.doi.org/10.1021/acs.orglett.2c03756

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