Importance of interface open circuit potential on aqueous hydrogenolytic reduction of benzyl alcohol over Pd/C

The open circuit potential (OCP) established by the quasi-equilibrated electrode reaction of H(2) and H(3)O(+)((hydr.)), complicates catalytic reactions significantly. The hydrogenolysis rate of benzylic alcohol on Pd/C increases 2-3 orders of magnitude with the pH decreasing from 7 to 0.6. The reac...

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Detalles Bibliográficos
Autores principales: Cheng, Guanhua, Zhang, Wei, Jentys, Andreas, Ember, Erika E., Gutiérrez, Oliver Y., Liu, Yue, Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9794693/
https://www.ncbi.nlm.nih.gov/pubmed/36575187
http://dx.doi.org/10.1038/s41467-022-35554-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9794693/
https://www.ncbi.nlm.nih.gov/pubmed/36575187
http://dx.doi.org/10.1038/s41467-022-35554-1

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