Cargando…
Importance of interface open circuit potential on aqueous hydrogenolytic reduction of benzyl alcohol over Pd/C
The open circuit potential (OCP) established by the quasi-equilibrated electrode reaction of H(2) and H(3)O(+)((hydr.)), complicates catalytic reactions significantly. The hydrogenolysis rate of benzylic alcohol on Pd/C increases 2-3 orders of magnitude with the pH decreasing from 7 to 0.6. The reac...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9794693/ https://www.ncbi.nlm.nih.gov/pubmed/36575187 http://dx.doi.org/10.1038/s41467-022-35554-1 |