Cargando…

Unveiling the Cerium(III)/(IV) Structures and Charge-Transfer Mechanism in Sulfuric Acid

[Image: see text] The Ce(3+)/Ce(4+) redox couple has a charge transfer (CT) with extreme asymmetry and a large shift in redox potential depending on electrolyte composition. The redox potential shift and CT behavior are difficult to understand because neither the cerium structures nor the CT mechani...

Descripción completa

Detalles Bibliográficos
Autores principales: Buchanan, Cailin A., Herrera, Dylan, Balasubramanian, Mahalingam, Goldsmith, Bryan R., Singh, Nirala
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9795571/
https://www.ncbi.nlm.nih.gov/pubmed/36590268
http://dx.doi.org/10.1021/jacsau.2c00484