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Unveiling the Cerium(III)/(IV) Structures and Charge-Transfer Mechanism in Sulfuric Acid
[Image: see text] The Ce(3+)/Ce(4+) redox couple has a charge transfer (CT) with extreme asymmetry and a large shift in redox potential depending on electrolyte composition. The redox potential shift and CT behavior are difficult to understand because neither the cerium structures nor the CT mechani...
Autores principales: | Buchanan, Cailin A., Herrera, Dylan, Balasubramanian, Mahalingam, Goldsmith, Bryan R., Singh, Nirala |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9795571/ https://www.ncbi.nlm.nih.gov/pubmed/36590268 http://dx.doi.org/10.1021/jacsau.2c00484 |
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