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One‐Pot Catalytic Conversion of Lignin‐Derivable Guaiacols and Syringols to Cyclohexylamines

Cyclic primary amines are elementary building blocks to many fine chemicals, pharmaceuticals, and polymers. Here, a powerful one‐pot Raney Ni‐based catalytic strategy was developed to transform guaiacol into cyclohexylamine using NH(3) (7 bar) and H(2) (10 bar) in up to 94 % yield. The methodology w...

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Detalles Bibliográficos
Autores principales: Wu, Xianyuan, De bruyn, Mario, Barta, Katalin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9796232/
https://www.ncbi.nlm.nih.gov/pubmed/35871610
http://dx.doi.org/10.1002/cssc.202200914