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Reactions of Diethylazo‐Dicarboxylate with Frustrated Lewis Pairs

Reactions of PAr(3)/B(C(6)F(5))(3) (Ar=o‐Tol, Mes, Ph) FLPs with diethyl azodicarboxylate (DEAD) afford the corresponding FLP addition products 1–3 in which P−N and B−O linkages are formed. In contrast, the reaction of BPh(3), PPh(3) and DEAD gave product 4 where P−N and N−B linkages were confirmed....

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Detalles Bibliográficos
Autores principales: Mandal, Dipendu, Chen, Ting, Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9796924/
https://www.ncbi.nlm.nih.gov/pubmed/35670767
http://dx.doi.org/10.1002/chem.202201701