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Rapid Access to Chiral and Tripodal Cavitands from β‐Pinene

We report Pd‐catalyzed cyclotrimerization of (+)‐α‐bromoenone, obtained from monoterpene β‐pinene, into an enantiopure cyclotrimer. This C (3) symmetric compound has three bicyclo[3.1.1]heptane rings fused to its central benzene with each ring carrying a carbonyl group. The cyclotrimer undergoes dia...

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Detalles Bibliográficos
Autores principales: Wang, Xiuze, Pavlović, Radoslav Z., Finnegan, Tyler J., Karmakar, Pratik, Moore, Curtis E., Badjić, Jovica D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9797447/
https://www.ncbi.nlm.nih.gov/pubmed/36168151
http://dx.doi.org/10.1002/chem.202202416