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High Intrinsic Phosphorescence Efficiency and Density Functional Theory Modeling of Ru(II)-Bipyridine Complexes with π-Aromatic-Rich Cyclometalated Ligands: Attributions of Spin–Orbit Coupling Perturbation and Efficient Configurational Mixing of Singlet Excited States
[Image: see text] A series of π-aromatic-rich cyclometalated ruthenium(II)-(2,2′-bipyridine) complexes ([Ru(bpy)(2)(π(Ar)-CM)](+)) in which π(Ar)-CM is diphenylpyrazine or 1-phenylisoquinoline were prepared. The [Ru(bpy)(2)(π(Ar)-CM)](+) complexes had remarkably high phosphorescence rate constants,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9798779/ https://www.ncbi.nlm.nih.gov/pubmed/36591186 http://dx.doi.org/10.1021/acsomega.2c07276 |