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Synthesis and Ring-Opening Metathesis Polymerization of o-Dialkoxy Paracyclophanedienes

[Image: see text] The highly strained ortho-diethylhexyloxy [2.2]paracyclophane-1,9-diene (M1) can be synthesized by ring contraction of a dithia[3.3]paracyclophane using a benzyne-induced Stevens rearrangement. This paracyclophanediene undergoes ring-opening metathesis polymerization to give well-d...

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Detalles Bibliográficos
Autores principales: Janpatompong, Yurachat, Spring, Andrew M., Komanduri, Venukrishnan, Khan, Raja U., Turner, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9798985/
https://www.ncbi.nlm.nih.gov/pubmed/36590370
http://dx.doi.org/10.1021/acs.macromol.2c02111