Taming Keteniminium Reactivity by Steering Reaction Pathways: Computational Predictions and Experimental Validations

[Image: see text] Keteniminium ions, the nitrogen analogues of ketenes, exhibit high reactivity toward olefins and π-systems. Previous results from the Maulide group demonstrated an unexpected propensity for an alternative intramolecular Belluš–Claisen-type rearrangement rather than an expected intr...

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Detalles Bibliográficos
Autores principales: Maskeri, Mark A., Fernandes, Anthony J., Di Mauro, Giovanni, Maulide, Nuno, Houk, K. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9801433/
https://www.ncbi.nlm.nih.gov/pubmed/36525680
http://dx.doi.org/10.1021/jacs.2c09146

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9801433/
https://www.ncbi.nlm.nih.gov/pubmed/36525680
http://dx.doi.org/10.1021/jacs.2c09146

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