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Taming Keteniminium Reactivity by Steering Reaction Pathways: Computational Predictions and Experimental Validations
[Image: see text] Keteniminium ions, the nitrogen analogues of ketenes, exhibit high reactivity toward olefins and π-systems. Previous results from the Maulide group demonstrated an unexpected propensity for an alternative intramolecular Belluš–Claisen-type rearrangement rather than an expected intr...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9801433/ https://www.ncbi.nlm.nih.gov/pubmed/36525680 http://dx.doi.org/10.1021/jacs.2c09146 |