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Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent‐Induced Dissociation Effects

Rare examples of heavier alkali metal manganates [{(AM)Mn(CH(2)SiMe(3))(N(‘Ar))(2)}(∞)] (AM=K, Rb, or Cs) [N(‘Ar)=N(SiMe(3))(Dipp), where Dipp=2,6‐iPr(2)‐C(6)H(3)] have been synthesised with the Rb and Cs examples crystallographically characterised. These heaviest manganates crystallise as polymeric...

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Detalles Bibliográficos
Autores principales: Ballmann, Gerd M., Gentner, Thomas X., Kennedy, Alan R., Hevia, Eva, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804227/
https://www.ncbi.nlm.nih.gov/pubmed/35775467
http://dx.doi.org/10.1002/chem.202201716