Thermally‐Activated Tunneling in the Two‐Water Bridge Catalyzed Tautomerization of Phosphinylidene Compounds

Phosphinylidenes are an important class of organophosphorus compounds that can exhibit tautomerization between tricoordinated P(III) hydroxide (R(1)R(2)POH) and a pentacoordinated P(V) oxide (R(1)R(2)P(O)H) form. Herein we show, using the canonical variational transition state theory combined with m...

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Detalles Bibliográficos
Autores principales: Nandi, Ashim, Martin, Jan M. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804263/
https://www.ncbi.nlm.nih.gov/pubmed/35867911
http://dx.doi.org/10.1002/cphc.202200396

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804263/
https://www.ncbi.nlm.nih.gov/pubmed/35867911
http://dx.doi.org/10.1002/cphc.202200396

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