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Thermally‐Activated Tunneling in the Two‐Water Bridge Catalyzed Tautomerization of Phosphinylidene Compounds
Phosphinylidenes are an important class of organophosphorus compounds that can exhibit tautomerization between tricoordinated P(III) hydroxide (R(1)R(2)POH) and a pentacoordinated P(V) oxide (R(1)R(2)P(O)H) form. Herein we show, using the canonical variational transition state theory combined with m...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804263/ https://www.ncbi.nlm.nih.gov/pubmed/35867911 http://dx.doi.org/10.1002/cphc.202200396 |