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α‐Thianthrenium Carbonyl Species: The Equivalent of an α‐Carbonyl Carbocation
Here we report an α‐thianthrenium carbonyl species, as the equivalent of an α‐carbonyl carbocation, which is generated by the radical conjugate addition of a trifluoromethyl thianthrenium salt to Michael acceptors. The reactivity allows for the synthesis of C(α)‐tetrasubstituted α‐ and β‐amino acid...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804271/ https://www.ncbi.nlm.nih.gov/pubmed/35895980 http://dx.doi.org/10.1002/anie.202208978 |